Portman, expecting her first child with choreographer Benjamin Millepied, was snapped by photographer Tim Walker for the ad campaign, due to appear in March.
In the ad, 28 year old, Portman covers herself with her arms and wears nothing but a black, bow headband. Screen advertisements for the perfume were directed by Sofia Coppola and reportedly show the actress kissing a younger male co-star.
"We are extremely excited to have Miss Portman embody our house," said Claude Martinez, president and chief executive officer of Parfums Christian Dior. "She will symbolize with grace the values of luxury and the glamour of Dior."
Portman is currently promoting her new Ashton Kutcher comedy, "No Strings Attached," which comes out on January 21. She will also star in the new medieval comedy, "Your Highness" alongside James Franco and Danny McBride, which is to be released on April 8, 2011.
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